trans-Dichloridobis{tris[4-(trifluoromethyl)phenyl]phosphane-κP}palladium(II) dichloromethane monosolvate
نویسندگان
چکیده
منابع مشابه
trans-Dibromidobis(triphenylphosphane)platinum(II) chloroform monosolvate
Both the platininum complex and the solvent mol-ecule of the title compound, [PtBr(2)(C(18)H(15)P)(2)]·CHCl(3), are located on a twofold rotation axis. The CH unit and the Cl atoms of the CHCl(3) mol-ecule are disordered over two equally occupied positions. The complex shows a trans square-planar geometry about the Pt atom.
متن کامل6,7,8,14,15,16-Hexaphenyldibenzo[c,gh]naphtho[3,2,1,8-pqra]tetraphene-5,13-dione dichloromethane monosolvate
The main mol-ecule of the title compound, C(66)H(38)O(2)·CH(2)Cl(2), is centrosymmetric, the asymmetric unit is composed of two half-mol-ecules, located on inversion centers, and a mol-ecule of dichloro-methane. The large π-conjugated fused polycyclic system including eight six-membered rings is nearly planar, with r.m.s. deviations of 0.2114 and 0.2081 Å in the two independent mol-ecules.
متن کاملtrans-Carbonylchloridobis[dicyclohexyl(4-isopropylphenyl)phosphane]rhodium(I) acetone monosolvate
The title rhodium Vaska-type complex, trans-[RhCl{P(C(6)H(11))(2)(C(6)H(4)-4-C(3)H(7))(2)}(2)(CO)], crystallizes with an accompanying acetone solvent mol-ecule. The metal atom shows a distorted square-planar coordination environment with selected important geometrical parameters of Rh-P = 2.3237 (6) and 2.3253 (6) Å, Rh-Cl = 2.3724 (6) Å, Rh-C = 1.802 (2) Å, P-Rh-P = 173.42 (2)° and Cl-Rh-C = 1...
متن کاملtrans-Carbonylchloridobis[tris(4-chlorophenyl)phosphane]rhodium(I) acetone monosolvate
The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P-Rh-P angle of 175.27 (2)° and Rh-P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solve...
متن کاملtrans-Dichloridobis[tris(4-methoxyphenyl)phosphine]palladium(II) benzene monosolvate
The structure of the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)]·C(6)H(6), shows a square-planar geometry for the Pd(II) atom within a Cl(2)[P(PhOMe)(3)](2) ligand set. The crystal structure contains benzene as solvent. The Pd(II) atom sits on a centre of inversion and therefore the asymmetric unit contains the Pd(II) atom, one Cl atom, one tris-(4-methoxy-phen-yl)phosphine ligand and one hal...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812046971